Reduction of Some 7-Halonorcaranes with Tri-n-butyltin Hydride
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چکیده
منابع مشابه
EFFICIENT PHOSPHOROUS-SULFUR BOND REDUCTION IN BICYCLIC THIAPHOSPHORANES WITH TRI-n-BUTYLTIN HYDRIDE
High yield photolytic reduction of a series of thiaphosphoranes Z p SR to give Z p H with UV-light-induced tri-n-butyltin hydride through phosphoranyl radical Z p is described. This reaction is inhibited by a-methylstyrene and initiated by a radical initiator such as azobisisobutyronitrile
متن کاملefficient phosphorous-sulfur bond reduction in bicyclic thiaphosphoranes with tri-n-butyltin hydride
high yield photolytic reduction of a series of thiaphosphoranes z p sr to give z p h with uv-light-induced tri-n-butyltin hydride through phosphoranyl radical z p is described. this reaction is inhibited by a-methylstyrene and initiated by a radical initiator such as azobisisobutyronitrile
متن کاملSynthesis, characterization and reactivity ratio study of poly(di(tri-n-butyltin) citraconate-co-N-vinylimidazole).
The organotin monomer di(tri-n-butyltin) citraconate (DTBTC, I) was synthesized. Subsequently this monomer was copolymerized with N-vinylimidazole (VI) using a free radical technique. The overall conversion was kept low (< or = 14% wt/wt) for all studied samples and the copolymer composition was determined from tin analysis using the Gilman and Rosenberg method. The synthesized monomer and copo...
متن کاملInfluence of the conformation of methoxy-(2-naphthyl)acetates (2NMA esters) on their chemical reactions.
An SN2 reaction (NaI) of 1,7-di(methanesulfoxyl)heptadien-4-yl methoxy-(2-naphthyl)acetate and a tributyltin hydride reduction of 1,7-diiodo-4-yl methoxy-(2-naphthyl)acetate (2NMA) is crucial for determination of the absolute configuration of secondary alcohols.
متن کاملEffects of bis (tri-n-butyltin) oxide on the eyes of rabbits.
Bis(tri-n-butyltin) oxide and its various commercial preparations are widely used because of their bactericidal, fungicidal, algicidal, and insecticidal properties (Barnes and Stoner, 1958; Barnes and Stoner, 1959; Elsea and Paynter, 1958; van der Kerk and Luijten, 1954). The commercial preparations of TBTO' are used in industry and in agriculture and as disinfectants in hygiene services (Asche...
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1972
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.45.1576